An International Double-Blind, Peer-Review Journal by NSTRI

Document Type : Research paper


1 Atomic & Molecular Group, Physics Factually, Yazd University, Yazd, Iran

2 Nuclear Science and Technology Research Institute (NSTRI), Tehran, Iran

3 Department of General Surgery, Shahid Sdoughi Hospital, Shahid Sdoughi University of Medical Sciences, Yazd, Iran


In this paper, we studied the effect of electron beam irradiation on the fabric to increase longevity of antibacterial coating and perfume release and measure it using the optical properties of the fabric. In other words, instead of using chemical compounds in the antibacterial coating and perfume structure, the change in the structural properties of the fabric as a substrate of antibacterial coating and perfume was examined. Three different types of fabrics, including fabric with polyester and cotton, fabric with felt and flannelette, and fabric with flannelette and cotton floss were irradiated at different doses without alcohol and in the presence of alcohol (96% ethanol) at an energy of 10 MeV with an electron beam of the Rhodotron accelerator TT200. Then, these three types of fabrics were impregnated with antibacterial coating and perfume after washing with cold water. Finally, the longevity of antibacterial coating and perfume on them was measured by using the Particle Density Reflection Parameters and He-Ne laser with a wavelength of 632 nm and a power of 5 mW. Experimental results showed that electron beam irradiation of the fabric in the presence of alcohol enhanced this property.


1.‎ Kuhnt, T., et al., Functionalized cellulose nanocrystals as nanocarriers for sustained ‎fragrance release. Polymer Chemistry, 2015. 6(36): p. 6553-6562.‎
2.      Frérot, E., K. Herbal, and A. Herrmann, Controlled Stepwise Release of Fragrance Alcohols ‎from Dendrimer‐Based 2‐Carbamoylbenzoates by Neighbouring Group Participation. ‎European Journal of Organic Chemistry, 2003. 2003(6): p. 967-971.‎
3.    Lage Robles, J. and C.G. Bochet, Photochemical release of aldehydes from α-acetoxy ‎nitroveratryl ethers. Organic letters, 2005. 7(16): p. 3545-3547.‎
4.     Soottitantawat, A., et al., Microencapsulation of l-menthol by spray drying and its release ‎characteristics. Innovative Food Science & Emerging Technologies, 2005. 6(2): p. 163-170.
5.    Levrand, B., et al., Controlled release of volatile aldehydes and ketones by reversible ‎hydrazone formation - "classical" profragrances are getting dynamic. Chemical ‎Communications, 2006(28): p. 2965-2967.‎
6.      Feczkó, T., V. Kokol, and B. Voncina, Preparation and characterization of ethylcellulose-‎based microcapsules for sustaining release of a model fragrance. Macromolecular ‎research, 2010. 18(7): p. 636-640.‎
7.    Sansukcharearnpon, A., et al., High loading fragrance encapsulation based on a polymer-‎blend: preparation and release behavior. International journal of pharmaceutics, 2010. ‎‎391(1): p. 267-273.‎
8.    Tzhayik, O., A. Cavaco-Paulo, and A. Gedanken, Fragrance release profile from ‎sonochemically prepared protein microsphere containers. Ultrasonics sonochemistry, 2012. ‎‎19(4): p. 858-863.‎
9.        Ciobanu, A., et al., Cyclodextrin-intercalated layered double hydroxides for fragrance ‎release. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2013. 75(3-4): p. 333-‎‎339.‎
10.   Vaughn, J., et al., Encapsulated recyclable porous materials: an effective moisture-triggered ‎fragrance release system. Chemical Communications, 2013. 49(51): p. 5724-5726.‎
11.  Ferrero Vallana, F.M., et al., Ionic liquids as modulators of fragrance release in consumer ‎goods. New Journal of Chemistry, 2016. 40(12): p. 9958-9967.‎
12. Li, Y., et al., Heat‐resistant sustained‐release fragrance microcapsules. Journal of Applied ‎Polymer Science, 2014. 131(7).‎
13.   Li, Y., et al., Comparison of Release Behaviors of Fragrance/Hydroxypropyl-β-cyclodextrin ‎Inclusion Complex and Fragrance Microcapsules. Integrated Ferroelectrics, 2014. 152(1): p. ‎‎81-89.‎
14.    Liu, C. and K. Hayashi, Visualization of controlled fragrance release from cyclodextrin ‎inclusion complexes by fluorescence imaging. Flavour and Fragrance Journal, 2014. 29(6): p. ‎‎356-363.‎
15.   Kuhnt, T., et al., Controlled fragrance release from galactose-based pro-fragrances. RSC ‎Advances, 2014. 4(92): p. 50882-50890.
16. Cao, Z., et al., Synthesis of fragrance/silica nanocapsules through a sol–gel process in ‎miniemulsions and their application as aromatic finishing agents. Colloid and Polymer ‎Science, 2015. 293(4): p. 1129-1139.‎
17. Hosseinkhani, B., et al., Novel biocompatible nanocapsules for slow release of fragrances ‎on the human skin. New biotechnology, 2015. 32(1): p. 40-46.‎
18.   Uhde, E. and N. Schulz, Impact of room fragrance products on indoor air quality. ‎Atmospheric Environment, 2015. 106: p. 492-502.‎
19.    Sánchez‐Navarro, M.M., et al., Scent properties by natural fragrance microencapsulation ‎for footwear applications. Polymer International, 2015. 64(10): p. 1458-1464.‎
20.  Tylkowski, B., et al. Photo‐Triggered Microcapsules. in Macromolecular Symposia. 2016. ‎Wiley Online Library.‎
21.   Lee, H., et al., Encapsulation and enhanced retention of fragrance in polymer ‎microcapsules. ACS applied materials & interfaces, 2016. 8(6): p. 4007-4013.‎
22.    Bashari, A., N. Hemmatinejad, and A. Pourjavadi, Smart and Fragrant Garment via Surface ‎Modification of Cotton Fabric With Cinnamon Oil/Stimuli Responsive PNIPAAm/Chitosan ‎Nano Hydrogels. IEEE transactions on nanobioscience, 2017. 16(6): p. 455-462.‎
23.  Rubio, O.D., et al., Anti-odour and antibacterial fabric in textile goods. 2018, Google ‎Patents.‎
24.  Ega, S.K., S.K. Ghosh, and B. Mallik, Nano-particulate capsules and emulsions thereof ‎including fragrance by emulsion polymerization. 2017, Google Patents.‎
25.  Chen, J., Y.-C. Nho, and J.-S. Park, Grafting polymerization of acrylic acid onto preirradiated ‎polypropylene fabric. Radiation Physics and Chemistry, 1998. 52(1-6): p. 201-206.‎
26.   Kumar, V., et al., Radiation-induced grafting of vinylbenzyltrimethylammonium chloride ‎‎(VBT) onto cotton fabric and study of its anti-bacterial activities. Radiation Physics and ‎Chemistry, 2005. 73(3): p. 175-182.‎
27.  Yang, J.M., et al., Wettability and antibacterial assessment of chitosan containing ‎radiation‐induced graft nonwoven fabric of polypropylene‐g‐acrylic acid. Journal of ‎Applied Polymer Science, 2003. 90(5): p. 1331-1336.‎
28.‎          Kavaklı, P.A., et al., Radiation‐induced graft polymerization of glycidyl methacrylate onto ‎PE/PP nonwoven fabric and its modification toward enhanced amidoximation. Journal of ‎applied polymer science, 2007. 105(3): p. 1551-1558.‎
29.  Blouin, F.A. and J.C. Arthur Jr, The effects of gamma radiation on cotton: Part I: some of ‎the properties of purified cotton irradiated in oxygen and nitrogen atmospheres. Textile ‎Research Journal, 1958. 28(3): p. 198-204.‎
30.  Demint, R.J. and J.C. Arthur Jr, the effects of gamma radiation on cotton: Part III: base ‎exchange properties of irradiated cotton. Textile Research Journal, 1959. 29(3): p. 276-278.‎
31.  Blouin, F.A. and J.G. Arthur Jr, The Effects of Gamma Radiation on Cotton: Part V: Post-‎Irradiation Reactions. Textile Research Journal, 1963. 33(9): p. 727-738.‎
32. Reinhardt, R.M. and J.A. Harris, Ultraviolet Radiation in Treatments for Imparting ‎Functional Properties to Cotton Textiles 1. Textile Research Journal, 1980. 50(3): p. 139-147.‎
33.   Porter, B.R., et al., Effects of gamma, high-energy electron, and thermal neutron radiations ‎on the fibrillar structure of cotton fibers. Textile Research Journal, 1960. 30(7): p. 510-520.‎
34.  Teszler, O. and H.A. Rutherford, The Effect of Nuclear Radiation on Fibrous Materials: Part ‎I: Dacron Polyester Fiber'1. Textile Research Journal, 1956. 26(10): p. 796-801.‎
35.  Södergård, A., Perspectives on modification of aliphatic polyesters by radiation processing. ‎Journal of bioactive and compatible polymers, 2004. 19(6): p. 511-525.‎
‎36.‎          Hongwang, Q. and G. Huang, Mechanical behaviors of glass/polyester composites after UV ‎radiation. Journal of Composite Materials, 2011. 45(19): p. 1939-1943.‎
37.‎          Lekner, J. and M.C. Dorf, Why some things are darker when wet. Applied Optics, 1988. ‎‎27(7): p. 1278-1280.‎
38.‎          Hopkins, D.N., M. Maqbool, and M.S. Islam, Linear attenuation coefficient and buildup ‎factor of MCP-96 alloy for dose accuracy, beam collimation, and radiation protection. ‎Radiological physics and technology, 2012. 5(2): p. 229-236.‎
39.‎          Jongen, Y., et al. First Beam Test Results of the 10 MeV, 100 kW Rhodotron. in Proceedings ‎of EPAC. 1994.‎
40.‎          Defrise, D., et al., Technical status of the first industrial unit of the 10 MeV, 100 kW ‎Rhodotron. Radiation Physics and Chemistry, 1995. 46(4-6): p. 473-476.‎
41.‎          Butler, H., perfumery, in Poucher’s perfumes, cosmetics and soaps. 1993, Springer Science ‎& Business Media. p. 55.‎
42.‎          wikipedia.‎
43.‎          Crivello, J.V., UV and electron beam-induced cationic polymerization. Nuclear Instruments ‎and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, ‎‎1999. 151(1-4): p. 8-21.‎
44.‎          Hoffman, G., et al., Water Relations and Growth of Cotton as Influenced by Salinity and ‎Relative Humidity 1. Agronomy Journal, 1971. 63(6): p. 822-826.‎
45.‎          Ashkenani, H., et al., Preconcentration, speciation and determination of ultra-trace ‎amounts of mercury by modified octadecyl silica membrane disk/electron beam irradiation ‎and cold vapor atomic absorption spectrometry. Journal of hazardous materials, 2009. ‎‎161(1): p. 276-280